Library / Journals / Wiley / Applied Organometallic Chemistry
Copyright © 2009 John Wiley & Sons, Ltd.
TABLE OF CONTENTS
Volume 23 Issue 2 , Pages 51 - 90 (February 2009)
Full Papers
Hydrodebromination of bromoarenes using Grignard reagents catalyzed by metal ions (p 51-54)
Miao Shen, Wen-Hua Sun
Published Online: Nov 10 2008 4:05AM
DOI: 10.1002/aoc.1470
Metal salts/complexes are efficient catalysts in hydrodebrominating aryl bromides under mild reaction conditions in the presence of various alkyl Grignard reagents. The homocoupling of Grignard reagents was observed as byproducts in quantitative yields. | |
Synthesis, characterization and catalytic activity of novel Co(II) and Pd(II)-perfluoroalkylphthalocyanine in fluorous biphasic system; benzyl alcohol oxidation (p 55-61)
Metin Özer, Filiz Yilmaz, Hakan Erer, 
brahimani, Özer Bekaro
lu
Published Online: Nov 10 2008 4:07AM
DOI: 10.1002/aoc.1471
Tetrakis[heptadecafluorononyl] substituted metallophthalocyanine complexes have been prepared. The activity of both complexes as a catalyst was studied for benzyl alcohol oxidation. | |
Atmospheric pressure deposition of F-doped SnO2 thin films from organotin fluoroalkoxide precursors (p 62-67)
Kieran C Molloy, Joanne E Stanley
Published Online: Dec 11 2008 6:34AM
DOI: 10.1002/aoc.1472
Five tributyltin fluoroalkoxides Bu3SnORf [Rf = CH(CF3)2 (1), CH2CF3 (2), CH2C2F5 (3), CH2(CF2)3CF2H (4), CH2CH2F (5)] were synthesized and assessed as precursors for the APCVD of F-doped SnO2. | |
Conversion of carbon dioxide to cyclic carbonates using diimine Ru(II) complexes as catalysts (p 68-74)
Mahmut Ulusoy, Engin Çetinkaya, Bekir Çetinkaya
Published Online: Nov 28 2008 6:22AM
DOI: 10.1002/aoc.1473
Cationic diimine Ru(II) complexes were synthesized and tested as catalysts for the formation of cyclic organic carbonates from CO2 and epoxides. These complexes as homogenous catalysts selectively transformed to carbon dioxide to five-membered cyclic carbonates. The more electron donating group on the p-position of the imine ligand accelerated the reaction rate. | |
CuI/PPh3-catalyzed Sonogashira coupling reaction of aryl iodides with terminal alkynes in water in the absence of palladium (p 75-77)
Jin Tao Guan, Guang-Ao Yu, Lei Chen, Tan Qing Weng, Jing Jing Yuan, Sheng Hua Liu
Published Online: Dec 3 2008 5:05AM
DOI: 10.1002/aoc.1474
A simple, practical and economical CuI/PPh3-catalyzed Sonogashira reaction of aryl iodides with terminal alkynes in water has been developed. In the presence of CuI/PPh3,OH was used as base and aryl iodides were treated smoothly with alkynes to afford the corresponding products in moderate to excellent yields. | |
Synthesis, characterization and catalytic studies of ruthenium(II) chalconate complexes (p 78-85)
M. Muthukumar, P. Viswanathamurthi
Published Online: Dec 18 2008 10:13AM
DOI: 10.1002/aoc.1475
Stable ruthenium(II) chalconate complexes were synthesized and characterized. They were assigned an octahedral structure. The new complexes were found to be efficient oxidation and transfer hydrogenation catalysts. | |
Synthesis, crystal structure and properties of a new lanthanide-transition metal carbonyl cluster (p 86-90)
Jiehui Ye, Haiquan Su, Fenghua Bai, Yong Du, Yulong Zhang
Published Online: Dec 18 2008 10:13AM
DOI: 10.1002/aoc.1476
A new heterobimetallic complex containing lanthanide and transition metal carbonyl cluster, Sm2{OOCCCo3(CO)9}2{OOCCF3}4 {(CO)9Co3CCOOH}4 (see picture), has been synthesized and characterized. It was used as catalyst precursor for hydrogenation of carbon monoxide reaction, which exhibits higher activity and remarkable selectivity than its bulk counterpart prepared by the conventional technique. | |